Quick re-read so sorry if I'm missing something.
Fan clutch on a van should be OE an HD style with a bi-metal spring which needs to be clean. From heat it allows fan to pull like a Cessna taking off and at speed of vehicle air flow is sometimes enough.
IMO - fan clutches are losing 10% per year in efficiency. If known 5 years old or older it's probably compromised already.
DON'T ADD REFRIGERANT TILL YOU FULLY UNDERSTAND IF IT NEEDS ANY!!!!! Overdoing it causes more trouble and hair loss than taking the time to understand it!
Top of this section is a good discussion on charging a system. Worth the read and know links were not yet on line when posted.
Air flow allows for refrigerant to condense to a liquid to be evaporated later at the right place and time. When and if compressed gas doesn't allow proper amount of liquid to return thru system it will suffer and more-so with dual A/C as rear will hog the bounty as said. Once front alone can operate properly, then you can blast the rear and pressures can go nuts so outputs vent temps are an important observation. Don't guess - measure the temps!
You can mist the condenser with water and watch for results. It will almost always perform better but if that trick totally corrects outputs temps then you need to dig into diagnosing why if extreme. No automotive A/C should be too low on charge or too high. It really wants to be just right,
T
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Tom Greenleaf - MetroWest, Boston